Between low self-discharge NiMH and Li-ion, 13 of the 16 characteristics in the full table below differ; one is the same and 2 can’t be compared because our sources give no figure or rating for one or both.
Rechargeable
NiMH low self-discharge
1.2 V · 84 Wh/kg · 2,100 cycles
An AA or AAA you can recharge up to 2,100 times that still holds 70 % after 10 years in a drawer.
Watch out: 1.2 V instead of 1.5 V: a few devices show a low battery early. Panasonic advises against devices with airtight battery compartments.
Rechargeable
Li-ion (NMC/NCA)
3.6 V · 221–260 Wh/kg · 400 cycles
The most energy per kilogram among rechargeables, in standard 18650 and 21700 cells with high-capacity and high-current versions.
Watch out: No charging below 0 °C, and a damaged or shorted cell can catch fire: use protected cells or a BMS.
Full comparison
Feature
NiMH low self-discharge
Li-ion (NMC/NCA)
Differences (13)
Basics
Nominal voltage
1.2 V
3.6 V
Voltage range
0.9 V (empty) to 1.4 V (full)
2.5 V (empty) to 4.2 V (full)
Formats
AA and AAA
18650 and 21700 cylindrical cells, alone or in packs
Example (source of the figures)
Panasonic eneloop AA
LG MJ1, Molicel P42A
Energy
Energy per kilogram
84 Wh/kg
221–260 Wh/kg
Energy per litre
273 Wh/L
597–727 Wh/L
Life and storage
Cycle life
Up to 2,100 (IEC 61951-2:2011); 600 with the 2017 method (Panasonic)
400 to 80 % (LG MJ1); not stated for the Molicel P42A
Self-discharge and storage
70 % left after 10 years at 20 °C (Panasonic estimate)
At most 10 % in 30 days at 25 °C (LG MJ1 test)
Temperature
Charging temperature
0–40 °C · fast charge (Panasonic BK-3MCC)
0–45 °C
Discharge temperature
from −20 to 50 °C · rated for use (Panasonic)
from −40 to 60 °C · LG MJ1 from −20 °C
Safety, charging and shipping
Charging
NiMH smart charger (2–3 hours) or 0.1C for 12–14 hours; trickle below C/40 (Energizer)
CC/CV to 4.20 V per cell, never above; packs need a BMS
Air transport
Not restricted by air when the terminals are protected against short circuits (IATA special provisions A199 for NiMH, A123 for dry cells)
Lithium-ion dangerous goods (UN3480/3481): loose batteries by cargo aircraft only, at 30 % charge at most; since 2026, batteries over 2.7 Wh packed with equipment must also be at 30 % at most. Passengers carry spares in the cabin, up to 100 Wh freely and 100–160 Wh with airline approval; since 27 March 2026, at most two power banks each, not recharged on board
Uses
Typical uses
Remotes, toys, game controllers, camera flashes, wireless keyboards
Power tools, e-bikes, laptops, flashlights, ESP32 projects on 18650 cells
Same on both (1)
Basics
Type
Rechargeable
Can’t be compared (2)
Current
Maximum continuous discharge
Not stated in our sources
From 10 A (2.9C, LG MJ1) to 45 A (10.7C, Molicel P42A)
Safety, charging and shipping
Fire risk
Not rated here
Higher: NCA cells went into thermal runaway at 207 °C and peaked at 579 °C in 18650 abuse tests; a short or an overcharge can start a fire
Choose low self-discharge NiMH for
more cycles (2,100 against 400)
long storage, with less self-discharge
easier air transport, without dangerous-goods rules
the AA/AAA format
Choose Li-ion for
more energy per kilogram (221–260 Wh/kg against 84 Wh/kg)
more energy per litre (597–727 Wh/L against 273 Wh/L)
What is the difference between low self-discharge NiMH and Li-ion?
With low self-discharge NiMH: more cycles, long storage, easier air transport, and the AA/AAA format. With Li-ion: more energy per kilogram, more energy per litre, and simple 5 V charging with a one-cell module.
Which lasts longer, low self-discharge NiMH or Li-ion?
Cycle life for low self-discharge NiMH: up to 2,100 (IEC 61951-2:2011); 600 with the 2017 method (Panasonic). For Li-ion: 400 to 80 % (LG MJ1); not stated for the Molicel P42A. These figures depend on depth of discharge, current and temperature.
Can I replace low self-discharge NiMH with Li-ion?
No: the voltage of Li-ion is 3.6 V per cell, against 1.2 V for low self-discharge NiMH, and in a device made for AA batteries it can do damage.