Aziz Bench

Lithium AA (Li-FeS₂) vs alkaline

Between lithium AA cells (Li-FeS₂) and alkaline cells, 10 of the 16 characteristics in the full table below differ; 5 are the same and one can’t be compared because our sources give no figure or rating for one or both.

Single use (primary)

Lithium AA (Li-FeS₂)

1.5 V · ≈ 310 Wh/kg · Single use

A 1.5 V AA that weighs 15 g, works from −40 to 60 °C and has a 25-year shelf life.

Watch out: Single use, and lithium-metal shipping rules apply (under 1 g of lithium per cell).

Single use (primary)

Alkaline

1.5 V · Single use

1.5 V, sold everywhere and 10 years on the shelf: fine for low-drain devices you rarely touch.

Watch out: The usable capacity depends strongly on the load, it works only down to −18 °C, and it is single use.

Full comparison

FeatureLithium AA (Li-FeS₂)Alkaline
Differences (10)
Basics
Voltage range1.5 V nominal; Energizer rates the capacity down to 1.0 V1.5 V nominal; Energizer’s tests stop at 0.8 V
FormatsAA and AAAAA, AAA, C, D and 9 V
Example (source of the figures)Energizer L91 (AA)Energizer E91 (AA)
Energy
Energy per kilogram≈ 310 Wh/kgNo single figure: the capacity depends strongly on the load (Energizer gives it as a chart)
Energy per litre≈ 563 Wh/LNo single figure: the capacity depends strongly on the load (Energizer gives it as a chart)
Life and storage
Self-discharge and storageShelf life 25 years at 21 °C (Energizer)Shelf life 10 years at 21 °C (Energizer E91; 12 years on the newer E91 Max sheet)
Current
Maximum continuous discharge2.5 A, 4 A in 2 s pulses (Energizer L91)No rated maximum; internal resistance 150–300 mΩ when fresh (Energizer)
Temperature
Discharge temperaturefrom −40 to 60 °Cfrom −18 to 55 °C
Safety, charging and shipping
Air transportLithium-metal dangerous goods (UN3090/3091): loose cells by cargo aircraft only; passengers may carry cells with up to 2 g of lithiumNot restricted by air when the terminals are protected against short circuits (IATA special provisions A199 for NiMH, A123 for dry cells)
Uses
Typical usesOutdoor sensors, trail cameras, GPS units, flashlights in the coldClocks, remotes, low-drain devices
Same on both (5)
Basics
TypeSingle use (primary)
Nominal voltage1.5 V
Life and storage
Cycle lifeSingle use
Temperature
Charging temperatureNot rechargeable
Safety, charging and shipping
ChargingNot rechargeable
Can’t be compared (1)
Safety, charging and shipping
Fire riskNot rated hereNot rated here

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Frequently asked questions

What is the difference between lithium AA cells (Li-FeS₂) and alkaline cells?

With lithium AA cells (Li-FeS₂): use in the cold and a longer rated shelf life. With alkaline cells: easier air transport.

Which lasts longer, lithium AA cells (Li-FeS₂) or alkaline cells?

Both are single use. Storage for lithium AA cells (Li-FeS₂): shelf life 25 years at 21 °C (Energizer). For alkaline cells: shelf life 10 years at 21 °C (Energizer E91; 12 years on the newer E91 Max sheet).

Can I replace alkaline cells with lithium AA cells (Li-FeS₂)?

In most devices, yes: both come as AA and AAA cells.

Other comparisons

Figures from one or two named cells or batteries per chemistry, from the makers’ datasheets; checked in November 2026.