Between Li-SOCl₂ and alkaline cells, 11 of the 16 characteristics in the full table below differ; 4 are the same and one can’t be compared because our sources give no figure or rating for one or both.
Single use (primary)
Li-SOCl₂
3.6 V · ≈ 560 Wh/kg · Single use
The most energy in an AA-size cell and under 1 % loss a year, from −60 to 85 °C: made for sensors that run for years.
Watch out: 3.6 V, not 1.5 V: it destroys devices made for AA batteries. Only 50 mA continuous, and after long storage the first pulses can sag (passivation): add a capacitor for radio bursts.
Single use (primary)
Alkaline
1.5 V · Single use
1.5 V, sold everywhere and 10 years on the shelf: fine for low-drain devices you rarely touch.
Watch out: The usable capacity depends strongly on the load, it works only down to −18 °C, and it is single use.
Full comparison
Feature
Li-SOCl₂
Alkaline
Differences (11)
Basics
Nominal voltage
3.6 V
1.5 V
Voltage range
3.67 V open circuit; capacity rated down to 2.0 V (Saft)
1.5 V nominal; Energizer’s tests stop at 0.8 V
Formats
AA size (14500) and other sizes, often with solder tags
AA, AAA, C, D and 9 V
Example (source of the figures)
Saft LS14500
Energizer E91 (AA)
Energy
Energy per kilogram
≈ 560 Wh/kg
No single figure: the capacity depends strongly on the load (Energizer gives it as a chart)
Energy per litre
≈ 1,100 Wh/L
No single figure: the capacity depends strongly on the load (Energizer gives it as a chart)
Life and storage
Self-discharge and storage
Under 1 % a year at 20 °C (Saft)
Shelf life 10 years at 21 °C (Energizer E91; 12 years on the newer E91 Max sheet)
Current
Maximum continuous discharge
50 mA, 250 mA in pulses (Saft LS14500)
No rated maximum; internal resistance 150–300 mΩ when fresh (Energizer)
Temperature
Discharge temperature
from −60 to 85 °C
from −18 to 55 °C
Safety, charging and shipping
Air transport
Lithium-metal dangerous goods (UN3090/3091): loose cells by cargo aircraft only; passengers may carry cells with up to 2 g of lithium
Not restricted by air when the terminals are protected against short circuits (IATA special provisions A199 for NiMH, A123 for dry cells)
Uses
Typical uses
Sensors that run for years: meters, LoRaWAN nodes, alarms, trackers
Clocks, remotes, low-drain devices
Same on both (4)
Basics
Type
Single use (primary)
Life and storage
Cycle life
Single use
Temperature
Charging temperature
Not rechargeable
Safety, charging and shipping
Charging
Not rechargeable
Can’t be compared (1)
Safety, charging and shipping
Fire risk
Not rated here
Not rated here
Choose Li-SOCl₂ for
use in the cold (from −60 °C, against −18 °C)
Choose alkaline cells for
easier air transport, without dangerous-goods rules
What is the difference between Li-SOCl₂ and alkaline cells?
With Li-SOCl₂: use in the cold. With alkaline cells: easier air transport and the AA/AAA format.
Which lasts longer, Li-SOCl₂ or alkaline cells?
Both are single use. Storage for Li-SOCl₂: under 1 % a year at 20 °C (Saft). For alkaline cells: shelf life 10 years at 21 °C (Energizer E91; 12 years on the newer E91 Max sheet).
Can I replace alkaline cells with Li-SOCl₂?
No: the voltage of Li-SOCl₂ is 3.6 V per cell, against 1.5 V for alkaline cells, and in a device made for AA batteries it can do damage.